分类： 物理学 >> 凝聚态:结构、力学和热性能 提交时间： 2017-03-26
摘要： Fe–0.6%Cu alloy was irradiated with H ions to 0.1 dpa, and then annealed for 30 min from 150 oC to 500 oC. We focused the evolution of Cu precipitates in irradiated Fe–0.6%Cu alloy after the isochronal annealing from the perspective of positron annihilation. The ΔW parameters after thermal annealing (400 oC and 500 oC) were much larger than that induced by 0.1 dpa H irradiation. Annealing could promote the aggregation of the Cu-vacancy complexes, and form the Cu cluster–vacancies complexes. When the vacancy-like defects recovered around 500 oC, it meant the formation and growing of the defect-free Cu precipitates.
分类： 物理学 >> 凝聚态:结构、力学和热性能 提交时间： 2017-03-23
Jing Zhang
Abu Zayed Mohammad Saliqur Rahman
Yuxiao Li
Jing Yang
Yaru Wu
Daqing Yuan
Xingzhong Cao
Runsheng Yu
Baoyi Wang
摘要： A comparative study on the morphology, structure and luminescence modifications of LDPE–Na2SO4:Sm3+ composite induced by gamma irradiation was reported for the first time. The composites were irradiated with irradiation doses of 10, 30, and 50 kGy in air at room temperature. Modifications on structural and luminescence properties of LDPE–Na2SO4:Sm3+ composites were investigated by using several analytical methods. The X-ray diffraction (XRD) patterns revealed that the cross-linking improved the crystallinity of the composites. Scanning electron microscope (SEM) images illustrated the surface modifications of composites induced by irradiation. Results of positron annihilation lifetime spectroscopy (PALS) suggested that gamma irradiation affected the free volumes concentrations in the samples. The photoluminescence (PL) spectra of non-irradiated and irradiated composites consisted of four main peaks at 563, 598, 644 and 706 nm which could be assigned to the 4G5/2 6HJ (J =5/2, 7/2, 9/2 and 11/2, respectively) transitions within the electronic configuration of Sm3+. Meanwhile, we observed an additional peak at about 686 nm in the irradiated composites, owing to the conversion of Sm3+ Sm2+. Concentrations of the Sm2+ centers linearly increased with gamma irradiation doses, which partly accounted for the degradation of PL intensity of Sm3+ peaks.
分类： 物理学 >> 凝聚态:结构、力学和热性能 提交时间： 2017-03-23
摘要： The effect of annealing on VmHn complexes and Cu precipitate behaviors in hydrogen ion irradiated Fe and Fe-0.3%Cu alloys was investigated by positron annihilation spectroscopy using a slow positron beam. The results of S parameters indicated that the room temperature irradiation was benefit for the formation of the VmHn complex compared to the elevated temperature irradiation. The S-W results confirmed the formation of Cu precipitates in Fe-0.3%Cu even at the irradiation dose of 0.1 dpa. The formation of the evident S value peaks in the damage region after annealing treatment suggested that the VmHn complexes were broken and a larger of hydrogen atoms were escaping. The residual vacancy defects would migrate towards both the surface region and the opposite direction with the increasing annealing temperature.
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